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A Study of Effect of Dye Structure on Polyelectrolyte Induced Metachromasy

Received: 30 August 2014     Accepted: 7 September 2014     Published: 23 September 2014
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Abstract

The interaction of two cationic dyes, namely, Azure B (AB) and Pinacyanol chloride (Pcyn) with an anionic polyelectrolyte, namely, sodium carrageenate (NaCar) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between Azure B and sodium carrageenate was found to be lesser than that formed between Pinacyanol chloride and sodium carrageenate. This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes. The interaction parameters revealed that binding between Azure B and sodium carrageenate was mainly due to electrostatic interaction while that between Pinacyanol chloride and carrageenate is found to involve both electrostatic and hydrophobic forces. The effect of the structure of the dye and its relation to metachromasy has been discussed.

Published in Science Journal of Chemistry (Volume 2, Issue 6-2)

This article belongs to the Special Issue Polyelectrolytes & Dyes

DOI 10.11648/j.sjc.s.2014020602.11
Page(s) 1-7
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

Cationic Dyes, Metachromasy, Sodium Carrageenate, Dye Structure, Aggregation

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    Nandini Ratnakar. (2014). A Study of Effect of Dye Structure on Polyelectrolyte Induced Metachromasy. Science Journal of Chemistry, 2(6-2), 1-7. https://doi.org/10.11648/j.sjc.s.2014020602.11

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    ACS Style

    Nandini Ratnakar. A Study of Effect of Dye Structure on Polyelectrolyte Induced Metachromasy. Sci. J. Chem. 2014, 2(6-2), 1-7. doi: 10.11648/j.sjc.s.2014020602.11

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    AMA Style

    Nandini Ratnakar. A Study of Effect of Dye Structure on Polyelectrolyte Induced Metachromasy. Sci J Chem. 2014;2(6-2):1-7. doi: 10.11648/j.sjc.s.2014020602.11

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  • @article{10.11648/j.sjc.s.2014020602.11,
      author = {Nandini Ratnakar},
      title = {A Study of Effect of Dye Structure on Polyelectrolyte Induced Metachromasy},
      journal = {Science Journal of Chemistry},
      volume = {2},
      number = {6-2},
      pages = {1-7},
      doi = {10.11648/j.sjc.s.2014020602.11},
      url = {https://doi.org/10.11648/j.sjc.s.2014020602.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.s.2014020602.11},
      abstract = {The interaction of two cationic dyes, namely, Azure B (AB) and Pinacyanol chloride (Pcyn) with an anionic polyelectrolyte, namely, sodium carrageenate (NaCar) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between Azure B and sodium carrageenate was found to be lesser than that formed between Pinacyanol chloride and sodium carrageenate. This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes. The interaction parameters revealed that binding between Azure B and sodium carrageenate was mainly due to electrostatic interaction while that between Pinacyanol chloride and carrageenate is found to involve both electrostatic and hydrophobic forces. The effect of the structure of the dye and its relation to metachromasy has been discussed.},
     year = {2014}
    }
    

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  • TY  - JOUR
    T1  - A Study of Effect of Dye Structure on Polyelectrolyte Induced Metachromasy
    AU  - Nandini Ratnakar
    Y1  - 2014/09/23
    PY  - 2014
    N1  - https://doi.org/10.11648/j.sjc.s.2014020602.11
    DO  - 10.11648/j.sjc.s.2014020602.11
    T2  - Science Journal of Chemistry
    JF  - Science Journal of Chemistry
    JO  - Science Journal of Chemistry
    SP  - 1
    EP  - 7
    PB  - Science Publishing Group
    SN  - 2330-099X
    UR  - https://doi.org/10.11648/j.sjc.s.2014020602.11
    AB  - The interaction of two cationic dyes, namely, Azure B (AB) and Pinacyanol chloride (Pcyn) with an anionic polyelectrolyte, namely, sodium carrageenate (NaCar) has been investigated by Spectrophotometric method. The polymer induced metachromasy in the dyes resulting in the shift of the absorption maxima of the dyes towards shorter wavelengths. The stability of the complexes formed between Azure B and sodium carrageenate was found to be lesser than that formed between Pinacyanol chloride and sodium carrageenate. This fact was further confirmed by reversal studies using alcohols, urea surfactants and electrolytes. The interaction parameters revealed that binding between Azure B and sodium carrageenate was mainly due to electrostatic interaction while that between Pinacyanol chloride and carrageenate is found to involve both electrostatic and hydrophobic forces. The effect of the structure of the dye and its relation to metachromasy has been discussed.
    VL  - 2
    IS  - 6-2
    ER  - 

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Author Information
  • Department of Chemistry, MITE, Moodabidri-574 226 (DK), Karnataka, India

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